Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials

被引:620
作者
Carriazo, Daniel [1 ]
Concepcion Serrano, Maria [1 ]
Concepcion Gutierrez, Maria [1 ]
Luisa Ferrer, Maria [1 ]
del Monte, Francisco [1 ]
机构
[1] CSIC, ICMM, E-28049 Madrid, Spain
关键词
TRANSFER RADICAL POLYMERIZATION; IONIC LIQUID MONOMERS; ROOM-TEMPERATURE; IONOTHERMAL SYNTHESIS; FRONTAL POLYMERIZATION; POROUS CARBON; SOL-GEL; PHOTOPOLYMERIZATION KINETICS; HYDROTHERMAL SYNTHESIS; AMBIENT-TEMPERATURE;
D O I
10.1039/c2cs15353j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aim of this review is to provide an exposition of some of the most recent applications of deep-eutectic solvents (DESs) in the synthesis of polymers and related materials. We consider that there is plenty of room for the development of fundamental research in the field of DESs because their compositional flexibility makes the number of DESs susceptible of preparation unlimited and so do the range of properties that DESs can attain. Ultimately, these properties can be transferred into the resulting materials in terms of both tailored morphologies and compositions. Thus, interesting applications can be easily envisaged, especially in those fields in which the preparation of high-tech products via low cost processes is critical. We hope that the preliminary work surveyed in this review will encourage scientists to explore the promising perspectives offered by DESs.
引用
收藏
页码:4996 / 5014
页数:19
相关论文
共 203 条
[1]  
Abbot A. P., 2008, ELECTRODEPOSITION IO
[2]   Eutectic-based ionic liquids with metal-containing anions and cations [J].
Abbott, Andrew P. ;
Barron, John C. ;
Ryder, Karl S. ;
Wilson, David .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (22) :6495-6501
[3]   Application of hole theory to define ionic liquids by their transport properties [J].
Abbott, Andrew P. ;
Harris, Robert C. ;
Ryder, Karl S. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18) :4910-4913
[4]   Electrodeposition of zinc-tin alloys from deep eutectic solvents based on choline chloride [J].
Abbott, Andrew P. ;
Capper, Glen ;
McKenzie, Katy J. ;
Ryder, Karl S. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 599 (02) :288-294
[5]   Application of ionic liquids to the electrodeposition of metals [J].
Abbott, Andrew P. ;
McKenzie, Katy J. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (37) :4265-4279
[6]   Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].
Abbott, AP ;
Boothby, D ;
Capper, G ;
Davies, DL ;
Rasheed, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147
[7]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[8]   Design of improved deep eutectic solvents using hole theory [J].
Abbott, AR ;
Capper, G ;
Gray, S .
CHEMPHYSCHEM, 2006, 7 (04) :803-806
[9]   Thermal stability of polypyrrole prepared from a ternary eutectic melt [J].
Abthagir, PS ;
Saraswathi, R .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 92 (01) :21-26
[10]   Synthesis of Precision Ionic Polyolefins Derived from Ionic Liquids [J].
Aitken, Brian S. ;
Lee, Minjae ;
Hunley, Matthew T. ;
Gibson, Harry W. ;
Wagener, Kenneth B. .
MACROMOLECULES, 2010, 43 (04) :1699-1701