π-Deficient α-arylsulfonyl esters as soft nucleophiles in organic synthesis

被引：9

作者：

Alonso, DA ^{[1
]}

Nájera, C ^{[1
]}

Varea, M ^{[1
]}

机构：

[1] Univ Alicante, Dept Quim Organ, E-03080 Alicante, Spain

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 50期

关键词：

sulfones; PTC; aconitate; dialkylation;

D O I：

10.1016/S0040-4039(01)01920-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Different pi -deficient arylsulfonyl groups have been studied as candidates for the stabilization of a-sulfonyl esters. The 3,5-bis(trifluoromethyl)phenylsulfonyl group has been shown to be the best substituent for the stereoselective synthesis of E-aconitates by a dialkylation-dehydrosulfinylation integrated process under PTC conditions using K2CO3 as base. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：8845 / 8848

页数：4

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