2-{[3-(triethoxysilyl)propyl]amino}pyridine and derivatives

被引：7

作者：

Belousova, LI ^{[1
]}

Vlasova, NN ^{[1
]}

Pozhidaev, YN ^{[1
]}

Voronkov, MG ^{[1
]}

机构：

[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Irkutsk 664003, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2001年 / 71卷 / 12期

关键词：

Gold; SiO2; Platinum; Pyridine; Palladium;

D O I：

10.1023/A:1014228023843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2- {[3-(Triethoxysilyl)propyl]amino}pyridine is synthesized by condensation of [3-(triethoxysilyl)propyl]amine with 2-aminopyridine. Its peretherification with triethanolamine leads to 2-[(3-silatranylpropyl)amino]pyridine and hydrolytic copolycondensation with tetraethoxysilane to cross-linked organosilicon copolymer {SiO2.2[O1.5Si(CH2)(3)NHC6H4N]}(n). The latter in the medium of hydrochloric acid behaves as an anionite in respect of anionic chlorocomplexes of gold(III), platinum(IV), palladium(II) and rhodiumIII).

引用

页码：1879 / 1882

页数：4

共 11 条

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[3]

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[4]

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[7]

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[9]

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