Developments in nanostructured LiMPO4 (M = Fe, Co, Ni, Mn) composites based on three dimensional carbon architecture

被引：139

作者：

Dimesso, L. ^{[1
]}

Foerster, C. ^{[1
]}

Jaegermann, W. ^{[1
,5
]}

Khanderi, J. P. ^{[2
]}

Tempel, H. ^{[2
]}

Popp, A. ^{[2
]}

Engstler, J. ^{[2
]}

Schneider, J. J. ^{[2
]}

Sarapulova, A. ^{[1
,3
]}

Mikhailova, D. ^{[1
,3
]}

Schmitt, L. A. ^{[1
]}

Oswald, S. ^{[3
]}

Ehrenberg, H. ^{[4
]}

机构：

[1] Tech Univ Darmstadt, Dept Mat Sci, D-64287 Darmstadt, Germany

[2] Tech Univ Darmstadt, Eduard Zintl Inst Anorgan & Phys Chem Anorgan Che, D-64287 Darmstadt, Germany

[3] Inst Komplexe Mat IFW Dresden, D-01069 Dresden, Germany

[4] IAM, KIT, D-76344 Eggenstein Leopoldshafen, Germany

[5] Tech Univ Darmstadt, Ctr Smart Intelligence, D-64287 Darmstadt, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 15期

关键词：

SOL-GEL SYNTHESIS; CATHODE MATERIALS; LITHIUM BATTERIES; PHOSPHO-OLIVINES; PARTICLE-SIZE; POLYOL MEDIUM; LIFEPO4; ELECTRODES; TEMPERATURE; PERFORMANCE;

D O I：

10.1039/c2cs15320c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanostructured materials lie at the heart of fundamental advances in efficient energy storage and/or conversion, in which surface processes and transport kinetics play determining roles. This review describes recent developments in the synthesis and characterization of composites which consist of lithium metal phosphates (LiMPO4, M = Fe, Co, Ni, Mn) coated on nanostructured carbon architectures (unordered and ordered carbon nanotubes, amorphous carbon, carbon foams). The major goal of this review is to highlight new progress in using different three dimensional nanostructured carbon architectures as support for the phosphate based cathode materials (e. g.: LiFePO4, LiCoPO4) of high electronic conductivity to develop lithium batteries with high energy density, high rate capability and excellent cycling stability resulting from their huge surface area and short distance for mass and charge transport.

引用

页码：5068 / 5080

页数：13

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