Neutral and cationic nickel(II) complexes of phosphino-amines: [NiCl2(PMe(2)Ph)(PNMe(2))] and [NiCl(PMe(2)Ph)(PNMe(2))]PF6 (PNMe(2)=N,N'-dimethyl-2-(diphenylphosphino)aniline)

被引：8

作者：

Crociani, L

Refosco, F

Tisato, F

Gatto, S

Corain, B

机构：

[1] CNR,ICTIMA,I-35020 PADUA,ITALY

[2] UNIV PADUA,DIPARTIMENTO SCI FARMACEUT,I-35131 PADUA,ITALY

[3] UNIV AQUILA,DIPARTIMENTO CHIM INGN CHIM & MAT,I-67010 LAQUILA,ITALY

[4] CNR,CTR STUDIO STABILITA & REATT COMPOSTI COORDINAZ,I-35131 PADUA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1996年 / 249卷 / 02期

关键词：

crystal structures; nickel complexes; phosphino-amine complexes; chelate complexes; RING;

D O I：

10.1016/0020-1693(96)05334-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A neutral bidentate P,N-ligand combining a hard dimethylamino nitrogen and a soft phosphine phosphorus donor affords the neutral trigonal bipyramidal as well as the cationic square-planar nickel(II) complexes cis-[NiCl2(PMe(2)Ph)(PNMe(2))] and [NiCl(PMe(2)Ph)(PNMe(2))]PF6, respectively, The latter species exhibits an appreciable catalytic activity in propylene oligomerization in the presence of Et(2)AlCl as co-catalyst.

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收藏

页码：131 / 133

页数：3

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