AI-free Sn-beta zeolite as a catalyst for the selective reduction of carbonyl compounds (Meerwein-Ponndorf-Verley reaction)

被引:370
作者
Corma, A
Domine, ME
Nemeth, L
Valencia, S
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia, Spain
[2] UOP LLC, Des Plaines, IL 60017 USA
关键词
D O I
10.1021/ja012297m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The catalytic activity of Sn-Beta zeolite in the Meerwein-Ponndorf-Verley (MPV) reduction of carbonyl compounds with secondary alcohols was performed with quantitative yields to the corresponding alcohol. This heterogeneous catalyst exhibits activities and selectivities not observed before with other Me-zeolites. Copyright © 2002 American Chemical Society.
引用
收藏
页码:3194 / 3195
页数:2
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