Compression and thermal expansion of hexagonal graphite-like boron nitride up to 7 GPa and 1800 K

被引:85
作者
Solozhenko, VL [1 ]
Peun, T [1 ]
机构
[1] GEOFORSCHUNGSZENTRUM POTSDAM, D-14473 POTSDAM, GERMANY
关键词
boron nitride; high pressure; high temperature; compression; thermal expansion;
D O I
10.1016/S0022-3697(97)00037-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The lattice parameters of hexagonal graphite-like boron nitride (hBN) have been measured in the temperature range from 300 to 1800 K up to 7 GPa using energy-dispersive powder diffraction of synchrotron radiation. From the obtained p-V-T relation for hBN, the temperature dependence of isothermal bulk modulus (B-0[GPa] = 32.06(4) + 4.47(9).e(-(T[K] - 298)/298)) and pressure dependence of thermal expansion coefficient (beta x 10(6)[K-1] = 40.9(8) - 1.6(2).p[GPa]) have been derived. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1321 / 1323
页数:3
相关论文
共 9 条
[1]   EQUATION OF STATE OF SODIUM CHLORIDE [J].
DECKER, DL .
JOURNAL OF APPLIED PHYSICS, 1966, 37 (13) :5012-&
[2]   EFFECT OF PRESSURE ON EMF OF CHROMEL-ALUMEL AND PLATINUM-PLATINUM 10 PERCENT RHODIUM THERMOCOUPLES [J].
GETTING, IC ;
KENNEDY, GC .
JOURNAL OF APPLIED PHYSICS, 1970, 41 (11) :4552-&
[3]  
Kurdyumov A. V., 1972, Soviet Physics - Crystallography, V17, P534
[4]   The compressibility of media under extreme pressures [J].
Murnaghan, FD .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1944, 30 :244-247
[5]   AN X-RAY STUDY OF BORON NITRIDE [J].
PEASE, RS .
ACTA CRYSTALLOGRAPHICA, 1952, 5 (03) :356-&
[6]  
Shimomura O., 1985, Symposia of the Society for Experimental Biology, P351
[7]  
Solozhenko V.L., 1993, THESIS MOSCOW STATE
[8]   ISOTHERMAL COMPRESSION OF HEXAGONAL GRAPHITE-LIKE BORON-NITRIDE UP TO 12 GPA [J].
SOLOZHENKO, VL ;
WILL, G ;
ELF, F .
SOLID STATE COMMUNICATIONS, 1995, 96 (01) :1-3
[9]   ANISOTROPIC THERMAL-EXPANSION OF BORON-NITRIDE .1. EXPERIMENTAL RESULTS AND THEIR ANALYSIS [J].
YATES, B ;
OVERY, MJ ;
PIRGON, O .
PHILOSOPHICAL MAGAZINE, 1975, 32 (04) :847-857