Fire retardant halogen-antimony-clay synergism in polypropylene layered silicate nanocomposites

被引:219
作者
Zanetti, M
Camino, G
Canavese, D
Morgan, AB
Lamelas, FJ
Wilkie, CA
机构
[1] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy
[2] NIST, Fire Sci Div, Bldg & Fire Res Lab, Gaithersburg, MD 20899 USA
[3] Marquette Univ, Dept Phys, Milwaukee, WI 53201 USA
[4] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
关键词
D O I
10.1021/cm011124t
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nanocomposites of polypropylene-graft-maleic anhydride with organically modified clays have been prepared and characterized by X-ray diffraction and transmission electron microscopy. Their combustion behavior has been evaluated using oxygen consumption cone calorimetry. Synergy is observed between the nanocomposite formed and conventional vapor phase fire retardants, such as the combination of decabromodiphenyloxide and antimony oxide. The presence of bromine and antimony does not affect the heat release rate curves of the virgin polymer.
引用
收藏
页码:189 / 193
页数:5
相关论文
共 32 条
[1]  
*ASTM, D2863 ASTM
[2]  
Babrauskas V., 1995, Fire Mater, V19, P243, DOI [10.1002/fam.810190602, DOI 10.1002/FAM.810190602]
[3]  
BRIDLEY SW, 1980, CRYSTAL STRUCTURE CL
[4]  
CAMINO G, 1993, ATMOSPHERIC OXIDATIO
[5]  
Georlette P., 2000, FIRE RETARDANCY POLY
[6]   Polymer layered silicate nanocomposites [J].
Giannelis, EP .
ADVANCED MATERIALS, 1996, 8 (01) :29-&
[7]   Flammability properties of polymer - Layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites [J].
Gilman, JW ;
Jackson, CL ;
Morgan, AB ;
Harris, R ;
Manias, E ;
Giannelis, EP ;
Wuthenow, M ;
Hilton, D ;
Phillips, SH .
CHEMISTRY OF MATERIALS, 2000, 12 (07) :1866-1873
[8]  
GILMAN JW, 1998, CHEM TECHNOLOGY POLY
[9]  
JANSSENS M, 1992, HEAT RELEASE FIRE
[10]  
KATZ HS, 1987, HDB FILLERS PLASTICS