Highly emissive, nine-coordinate enantiopure lanthanide complexes incorporating tetraazatriphenylenes as probes for DNA

被引:64
作者
Bobba, G [1 ]
Frias, JC [1 ]
Parker, D [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
D O I
10.1039/b201451n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interaction of q = 0 Delta- and Lambda-Tb and Eu complexes with poly(dAdT), poly(dGdC) and calf-thymus DNA has been examined by absorption, emission and chiroptical spectroscopy and is sensitive to complex helicity, base-pair type and the nature of the lanthanide excited state.
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页码:890 / 891
页数:2
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