Production of cold formaldehyde molecules for study and control of chemical reaction dynamics with hydroxyl radicals

被引:104
作者
Hudson, Eric R. [1 ]
Ticknor, Christopher
Sawyer, Brian C.
Taatjes, Craig A.
Lewandowski, H. J.
Bochinski, J. R.
Bohn, J. L.
Ye, Jun
机构
[1] Joint Inst Lab Astrophys, Natl Inst Stand & Technol, Boulder, CO 80309 USA
[2] Univ Colorado, Dept Phys, Boulder, CO 80309 USA
[3] Sandia Natl Labs, JILA, VF Combust Res Facil, Livermore, CA 94551 USA
来源
PHYSICAL REVIEW A | 2006年 / 73卷 / 06期
关键词
D O I
10.1103/PhysRevA.73.063404
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We propose a method for controlling a class of low temperature chemical reactions. Specifically, we show the hydrogen abstraction channel in the reaction of formaldehyde (H2CO) and the hydroxyl radical (OH) can be controlled through either the molecular state or an external electric field. We also outline experiments for investigating and demonstrating control over this important reaction. To this end, we report the first Stark deceleration of H2CO. We have decelerated a molecular beam of H2CO essentially to rest, producing molecules at 100 mK with a density of similar to 10(6) cm(-3).
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页数:6
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