Palladium-catalyzed asymmetric allylic alkylation using (R)-2-(methoxymethyl)pyrrolidine-derived aminophosphine ligands

被引：39

作者：

Mino, T ^{[1
]}

Tanaka, Y ^{[1
]}

Sakamoto, M ^{[1
]}

Fujita, T ^{[1
]}

机构：

[1] Chiba Univ, Fac Engn, Dept Mat Technol, Inage Ku, Chiba 2638522, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 17期

关键词：

D O I：

10.1016/S0957-4166(01)00426-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate 7a using a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of new chiral aminophosphine ligands such as 4 in good yields with good enantioselectivities (up to 96 4, e.e.). (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2435 / 2440

页数：6

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