The first organoelement oxides containing three different metals;: synthesis and structure of (Ph2SiOR2SnOMO) [R = (CH2)3NMe2; M = Bu2tSn, Bu2tGe, PhB]

被引：15

作者：

Beckmann, J ^{[1
]}

Jurkschat, K ^{[1
]}

Pieper, N ^{[1
]}

Schürmann, M ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 12期

关键词：

D O I：

10.1039/a902428j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Umpolung of ring strain by intramolecular Sn-N Lewis acid-Lewis base interaction is the key for the synthesis of the first organoelement oxides of the type (Ph2SiOR2SnOMO) [R = (CH2)(3)NMe2; M = (Bu2Sn)-Sn-t, (Bu2Ge)-Ge-t, PhB] which hold potential as precursors to tertiary metal oxides.

引用

页码：1095 / 1096

页数：2

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