Luminescence kinetics of linear polymer molecules with chromophores randomly distributed along the chain

被引：5

作者：

Bodunov, EN ^{[1
]}

Berberan-Santos, MN

Martinho, JMG

机构：

[1] Russian State Hydrometeorol Univ, St Petersburg 195196, Russia

[2] Univ Tecn Lisboa, Ctr Phys Chem Mol, P-1049001 Lisbon, Portugal

来源：

OPTICS AND SPECTROSCOPY | 2001年 / 91卷 / 05期

关键词：

D O I：

10.1134/1.1420850

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Luminescence kinetics of chromophores randomly attached to an isolated flexible polymer chain is studied. In the static case, when the polymer chain does not change its conformation during the donor excited-state lifetime, analytical equations are derived for the luminescence kinetics of both ideal and nonideal polymer chains. The conditions are formulated when the inhomogeneous broadening should be taken into account. For the dynamic case, the diffusion and hopping mechanisms of the polymer motion are studied. (C) 2001 MAIK "Nauka/Interperiodica".

引用

页码：694 / 703

页数：10

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