In situ RHEED monitor of the growth of epitaxial anatase TiO2 thin films

被引:67
作者
Ong, CK
Wang, SJ
机构
[1] CSMM, Dept Phys, Singapore 119260, Singapore
[2] Natl Univ Singapore, Singapore 119260, Singapore
关键词
laser deposition; dielectric thin films; surfaces and interfaces; reflection high-energy electron diffraction;
D O I
10.1016/S0169-4332(01)00589-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Epitaxial anatase TiO2 thin films were successfully grown on (0 0 1) SrTiO3 substrates by the laser molecular-beam epitaxy (laser-MBE) method. The whole growth process is monitored by in situ reflection High-energy electron diffraction (RHEED). RHEED monitoring shows a transition from a streaky pattern to a spot pattern during deposition, indicating different growth a modes of TiO2 film. The RHEED patterns are in consistent with the RHEED intensity oscillation results. The atomic force microscopy (AFM) and X-ray diffraction (XRD) investigation show that the thin films have single crystalline orientation with roughness less than three unit cells. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:47 / 51
页数:5
相关论文
共 14 条
[1]   In situ reflection high-energy electron diffraction observation of epitaxial LaNiO3 thin films [J].
Chen, P ;
Xu, SY ;
Zhou, WZ ;
Ong, CK ;
Cui, DF .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (05) :3000-3002
[2]   OBSERVATION OF SURFACE PHONONS ON THE (001) AND (100) SURFACES OF ANATASE MINERALS [J].
DURINCK, G ;
POELMAN, H ;
CLAUWS, P ;
FIERMANS, L ;
VENNIK, J ;
DALMAI, G .
SOLID STATE COMMUNICATIONS, 1991, 80 (08) :579-581
[3]   Introductory lecture: Oxide surfaces [J].
Freund, HJ .
FARADAY DISCUSSIONS, 1999, 114 :1-31
[4]   Surface chemistry of titania (anatase) and titania-supported catalysts [J].
Hadjiivanov, KI ;
Klissurski, DG .
CHEMICAL SOCIETY REVIEWS, 1996, 25 (01) :61-+
[5]   LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].
HAGFELDT, A ;
GRATZEL, M .
CHEMICAL REVIEWS, 1995, 95 (01) :49-68
[6]   Structure and stability of the anatase TiO2 (101) and (001) surfaces [J].
Hengerer, R ;
Bolliger, B ;
Erbudak, M ;
Grätzel, M .
SURFACE SCIENCE, 2000, 460 (1-3) :162-169
[7]   Structure determination of the two-domain (1 x 4) anatase TiO2(001) surface [J].
Herman, GS ;
Sievers, MR ;
Gao, Y .
PHYSICAL REVIEW LETTERS, 2000, 84 (15) :3354-3357
[8]  
LAZZERI M, 2001, PHYS REV B, V63
[9]   Surface structure of anatase TiO2(001):: Reconstruction, atomic steps, and domains -: art. no. 235402 [J].
Liang, Y ;
Gan, SP ;
Chambers, SA ;
Altman, EI .
PHYSICAL REVIEW B, 2001, 63 (23)
[10]   PHOTOCATALYSIS ON TIO2 SURFACES - PRINCIPLES, MECHANISMS, AND SELECTED RESULTS [J].
LINSEBIGLER, AL ;
LU, GQ ;
YATES, JT .
CHEMICAL REVIEWS, 1995, 95 (03) :735-758