Graft copolymerization of polyester fibers with a fluorine-containing monomer

被引：13

作者：

Louati, M ^{[1
]}

ElAchari, A ^{[1
]}

Ghenaim, A ^{[1
]}

Caze, C ^{[1
]}

机构：

[1] Ecole Natl Super Arts & Ind Text, GEMTEX Lab, F-59100 Roubaix, France

来源：

TEXTILE RESEARCH JOURNAL | 1999年 / 69卷 / 05期

关键词：

D O I：

10.1177/004051759906900513

中图分类号：

TB3 [工程材料学]; TS1 [纺织工业、染整工业];

学科分类号：

0805 ; 080502 ; 0821 ;

摘要：

Polyester monofilaments are grafted with perfluorooctyl-2 ethanol acrylic monomer (AC8) ( C8F17-C2H4-O-CO-CH=CH2) to improve water and oil repellency and chemical and thermal stability and to enhance adhesion with a fluor matrix. Kinetic parameters like the percent grafting and grafting rate are measured as a function of monomer concentration, initiator concentration, and time and temperature of the reaction. The results show that the optimum graft yield is obtained for a monomer concentration of 1.125 moles/liter and for an initiator concentration of 1.8 10(-2) moles/liter. The impact of the graft modification is characterized by crystallinity and surface topography.

引用

页码：381 / 387

页数：7

共 18 条

[1] EFFECT OF GRAFT-COPOLYMERIZATION OF 2-HYDROXYETHYL METHACRYLATE ON THE PROPERTIES OF POLYESTER FIBERS AND FABRIC [J].

ABDELBARY, EM ;

SARHAN, AA ;

ABDELRAZIK, HH .

JOURNAL OF APPLIED POLYMER SCIENCE, 1988, 35 (02) :439-448

[2]

[Anonymous], 1993, COMM REF MAN VERS 3

[3]

BALASUBRAMANIAM B, 1995, JMS PURE APPL CHEM A, V32, P1025

[4] ATOMIC FORCE MICROSCOPE [J].

BINNIG, G ;

QUATE, CF ;

GERBER, C .

PHYSICAL REVIEW LETTERS, 1986, 56 (09) :930-933

[5] THERMAL-PROPERTIES OF WOOL-G-POLY(METHYL METHACRYLATE) COPOLYMERS [J].

ELANGOVAN, VJ ;

SACCUBAI, S .

JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 45 (10) :1823-1830

[6] THERMAL-CHARACTERISTICS OF POLY(ETHYLENE-TEREPHTHALATE) FIBER GRAFTED WITH POLYVINYL ACETATE) AND POLYVINYL-ALCOHOL) [J].

FATERPEKER, SA ;

POTNIS, SP .

JOURNAL OF APPLIED POLYMER SCIENCE, 1982, 27 (09) :3349-3356

[7] GRAFT-POLYMERIZATION OF METHYL-METHACRYLATE ON POLY(ETHYLENE-TEREPHTHALATE) FIBERS USING H2O2 AS INITIATOR [J].

HEBEISH, A ;

SHALABY, SE ;

BAYAZEED, AM .

JOURNAL OF APPLIED POLYMER SCIENCE, 1981, 26 (10) :3253-3269

[8] THE INFLUENCE OF POLYMER-GRAFTED LIPIDS ON THE PHYSICAL-PROPERTIES OF LIPID BILAYERS - A THEORETICAL-STUDY [J].

HRISTOVA, K ;

NEEDHAM, D .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1994, 168 (02) :302-314

[9] GRAFTING ON POLYESTER FIBERS [J].

KALE, PD ;

LOKHANDE, HT ;

RAO, KN ;

RAO, MH .

JOURNAL OF APPLIED POLYMER SCIENCE, 1975, 19 (02) :461-480

[10] NOVEL FLUOROALKYLATION OF POLYESTER SURFACES - GRAFTING WITH PERFLUOROALKANOYL PEROXIDES [J].

KAWASE, T ;

FUJI, T ;

MINAGAWA, M ;

SAWADA, H ;

NAKAYAMA, M .

TEXTILE RESEARCH JOURNAL, 1994, 64 (07) :375-380

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