Crystal engineering of metalloporphyrin assemblies. New supramolecular architectures mediated by bipyridyl ligands

被引:55
作者
Diskin-Posner, Y [1 ]
Patra, GK [1 ]
Goldberg, I [1 ]
机构
[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel
关键词
D O I
10.1039/b202791g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Targeted synthesis of new supramolecular motifs of metalloporphyrins in crystals by a concerted mechanism of molecular recognition in three dimensions, aided by organic ligands, is presented; it involves induced assembly of [tetrakis(4-hydroxyphenyl) porphyrinato] zinc species by a combination of axial coordination through bridging bipyridyls and of lateral hydrogen bonding.
引用
收藏
页码:1420 / 1421
页数:2
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