Autoionization-detected infrared spectroscopy of jet-cooled aromatic cations in the gas phase:: CH stretching vibrations of isolated p-ethylphenol cations

被引：23

作者：

Fujii, A ^{[1
]}

Fujimaki, E ^{[1
]}

Ebata, T ^{[1
]}

Mikami, N ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 303卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(99)00227-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first observation of CH stretching vibrations of isolated aromatic molecular cations in the gas phase was performed by using autoionization-detected infrared (ADIR) spectroscopy. Aromatic and alkyl CH stretching vibrations of p-ethylphenol (p-EP) in the cationic ground state were observed and compared with those of the neutral ground state. Distinct high-frequency shifts of these vibrations upon ionization were found. CH stretching vibrations of the p-EP-Ar cluster cation were also measured by infrared photodissociation (IRPD) spectroscopy, providing essentially the same vibrational spectrum as that of the bare cation. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：289 / 294

页数：6

共 25 条

[1] Frisch M.J., 1995, GAUSSIAN 94 REVISION
[2] Autoionization-detected infrared spectroscopy of molecular ions
Fujii, A
Iwasaki, A
Ebata, T
Mikami, N
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (34) : 5963 - 5965
[3] INFRARED DISSOCIATION SPECTROSCOPY OF THE OH STRETCHING VIBRATION OF PHENOL RARE-GAS VAN-DER-WAALS CLUSTER IONS
FUJII, A
SAWAMURA, T
TANABE, S
EBATA, T
MIKAMI, N
[J]. CHEMICAL PHYSICS LETTERS, 1994, 225 (1-3) : 104 - 107
[4] A new type of intramolecular hydrogen bonding:: Hydroxyl-methyl interactions in the o-cresol cation
Fujii, A
Fujimaki, E
Ebata, T
Mikami, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (50) : 13256 - 13257
[5] Observation of intramolecular hydrogen bonds of o-fluorophenol ions by using autoionization detected infrared spectroscopy
Fujii, A
Iwasaki, A
Mikami, N
[J]. CHEMISTRY LETTERS, 1997, (11) : 1099 - 1100
[6] FUJIMAKI E, IN PRESS J CHEM PHYS
[7] FUJIMAKI E, UNPUB
[8] OH stretching vibrations in aromatic cations: IR/PIRI spectroscopy
Gerhards, M
Schiwek, M
Unterberg, C
Kleinermanns, K
[J]. CHEMICAL PHYSICS LETTERS, 1998, 297 (5-6) : 515 - 522
[9] Probing the photoinduced Rydberg ionization process
Goode, JG
LeClaire, JE
Johnson, PM
[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1996, 159 : 49 - 64
[10] Vibrational and electronic energy levels of polyatomic transient molecules. Supplement A
Jacox, ME
[J]. JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1998, 27 (02) : 115 - 393

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