Direct observation of ligand-centered redox in CP*2Rh2(μ-C2S4)Clx (x=2, 0)

被引：15

作者：

Holloway, GA ^{[1
]}

Rauchfuss, TB ^{[1
]}

机构：

[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 13期

关键词：

D O I：

10.1021/ic990150e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the first time, the structural chemistry of a M2C2S4 core has been elucidated in two oxidation states: two-electron reduction of Cp-2*Rh-2(mu-C2S4)Cl-2 (r(S2C-CS2) = 1.45 Angstrom) produces Cp-2*Rh-2(mu-C2S4) (r(S2C-CS2) = 1.34 Angstrom).

引用

页码：3018 / +

页数：3

共 14 条

[1] GENESIS OF TETRATHIOOXALATE-LIKE C2S4 AND C2SE4 UNITS - A MULTIFORM EXPERIMENTAL-STUDY AND THE RELEVANT THEORETICAL IMPLICATIONS FOR THE ROLE OF TRANSITION-METAL FRAGMENTS [J].

BIANCHINI, C ;

MEALLI, C ;

MELI, A ;

SABAT, M ;

ZANELLO, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (01) :185-198

[2] A new synthesis of tetrathiooxalate and its conversion to C3S52- and C4S62- [J].

Breitzer, JG ;

Chou, JH ;

Rauchfuss, TB .

INORGANIC CHEMISTRY, 1998, 37 (08) :2080-+

[3] REACTIONS OF CS2 WITH METAL CLUSTER CARBONYLS OF THE IRON TRIAD - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [FE4(CO)12(C2S4)] [J].

BROADHURST, PV ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (02) :140-141

[4] LATE TRANSITION-METAL SULFIDO COMPLEXES - REACTIVITY STUDIES AND MECHANISTIC ANALYSIS OF THEIR CONVERSION INTO METAL-SULFUR CUBANE COMPLEXES [J].

DOBBS, DA ;

BERGMAN, RG .

INORGANIC CHEMISTRY, 1994, 33 (23) :5329-5336

[5] RHODIUM-PERFLUOROBENZENETHIOLATO AND IRIDIUM-PERFLUOROBENZENETHIOLATO COMPLEXES, [(C5ME5)IR(SC6F5)2], [(C5ME5)IR(SC6F4H-P)2] AND [(C5ME5)2RH2(MU-SC6F5)3][(C5ME5)RH(SC6F5)3] - SYNTHESES, CRYSTAL-STRUCTURES AND SOLUTION BEHAVIOR [J].

GARCIA, JJ ;

TORRENS, H ;

ADAMS, H ;

BAILEY, NA ;

SHACKLADY, A ;

MAITLIS, PM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (10) :1529-1536

[6] TETRATHIO-OXALATE AS SIDE-ON BRIDGING LIGAND - CRYSTAL AND MOLECULAR-STRUCTURE OF MU-TETRATHIOOXALATO-BIS[BIS(TRIPHENYLPHOSPHINE)-COPPER(I)] [J].

HANSEN, LK ;

SIELER, J ;

STRAUCH, P ;

DIETZSCH, W ;

HOYER, E .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1985, 39 (08) :571-575

[7] TITANIUM-ACTIVATED CARBON-CARBON BOND FORMATION BY REDUCTIVE HEAD-TO-HEAD COUPLING OF CARBON-DISULFIDE - SYNTHESIS OF [(ETA-5-C5H5)2TI]2(C2S4) AND COMPARATIVE-ANALYSIS OF THIS ELECTRON-DELOCALIZED TETRATHIOLENE-BRIDGED DITITANIUM COMPLEX WITH THE ELECTRONICALLY EQUIVALENT, ELECTRON-LOCALIZED OXALATE AND TETRA-PARA-TOLYLOXALYLAMIDINE-BRIDGED DITITANIUM COMPLEXESI [J].

HARRIS, HA ;

RAE, AD ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) :4739-4741

[8] TETRATHIOOXALATE - ELECTROCHEMICAL PREPARATION AND X-RAY STRUCTURE DETERMINATION OF A TETRATHIOOXALATE [J].

LUND, H ;

HOYER, E ;

HAZELL, RG .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1982, 36 (03) :207-209

[9] TRANSITION-METAL-PROMOTED CARBON CARBON BOND FORMATION BY REDUCTIVE DIMERIZATION OF CARBON-DISULFIDE - DIRECT SYNTHESIS OF THE BIS(1,2-DITHIOLENE-LIKE) TETRATHIOOXALATO (C2S4) LIGAND FROM CARBON-DISULFIDE BY REACTION WITH THE DIMERIC NICKEL(I) COMPLEXES NI2(ETA-5-C5R5)2(MU-CO)2(R=H,ME) [J].

MAJ, JJ ;

RAE, AD ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (15) :4278-4280

[10] Electrically conducting materials based on mu-tetrathiooxalato-bridged bimetallic Ni(II) anionic complexes [J].

Pullen, AE ;

Zeltner, S ;

Olk, RM ;

Hoyer, E ;

Abboud, KA ;

Reynolds, JR .

INORGANIC CHEMISTRY, 1997, 36 (19) :4163-4171

← 1 2 →