The ionothermal synthesis of cobalt aluminophosphate zeolite frameworks

被引：250

作者：

Parnham, ER ^{[1
]}

Morris, RE ^{[1
]}

机构：

[1] Univ St Andrews, EaStChem Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 07期

关键词：

D O I：

10.1021/ja057933l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionothermal synthesis, the use of an ionic liquid as both solvent and structure-directing agent, has been used to synthesize three different cobalt aluminophosphate zeolites. Two of the materials are isostructural with solids prepared previously and have the AEI and SOD framework types. SIZ-7 is a novel zeolite structures that is closely related to the family of 8-ring zeolites consisting of the MER, GIS, and PHI frameworks. Single-crystal X-ray diffraction of SIZ-7 indicates that the distribution of cobalt among the four possible tetrahedral sites is unequal. Copyright © 2006 American Chemical Society.

引用

页码：2204 / 2205

页数：2

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