Single-Crystalline Hollow Face-Centered-Cubic Cobalt Nanoparticles from Solid Face-Centered-Cubic Cobalt Oxide Nanoparticles

被引:129
作者
Nam, Ki Min [1 ,2 ]
Shim, Jae Ha [1 ,2 ]
Ki, Hosung [1 ,2 ]
Choi, Sang-Il [1 ,2 ]
Lee, Gaehang [1 ,2 ]
Jang, Jae Kwon [1 ,2 ]
Jo, Younghun [3 ]
Jung, Myung-Hwa [3 ]
Song, Hyunjoon [1 ,2 ]
Park, Joon T. [1 ,2 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Taejon 305701, South Korea
[3] Korea Basic Sci Inst, Taejon 305303, South Korea
关键词
cobalt oxide; cobalt; hollow nanoparticles; magnetic properties; nanostructures;
D O I
10.1002/anie.200803048
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Hollow nan': Hollow face-centered cubic (fcc) Co nanoparallelepipeds were prepared by thermolysis of solid fcc CoO nanoparallelepipeds in oleylamine (see TEM image). The solid fcc CoO nanoparallelepipeds are reduced by the oleylamine surfactant to form hollow fcc Co nanoparallelepipeds. Voids and fcc Co are generated on the surface of the solid fcc CoO nanoparallelepipeds by the removal of oxide as carbon monoxide. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:9504 / 9508
页数:5
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