Mono-, di-, and trimetallic palladium(II) porphyrin trimers with etheno-bridges

被引：24

作者：

Higuchi, H

Takeuchi, M

Ojima, J

机构：

[1] Department of Chemistry, Faculty of Science, Toyama University, Toyamu 930, Gofuku

来源：

CHEMISTRY LETTERS | 1996年 / 08期

关键词：

D O I：

10.1246/cl.1996.593

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mono-, di-, and trimetallic Pd(II) complexes of the ethenobridge porphyrin trimer 1 were prepared. It was found that the metalation of 1 first occurred in the inner porphyrin ring. The trimetallic Pd(II) trimer 6 exhibited splitting of the Soret band and complete disappearance of the weak bands ranging from 600 to 1000 nm unlike the corresponding free-base and Ni(II) porphyrin trimers.

引用

页码：593 / 594

页数：2

共 8 条

[1] CONJUGATED PORPHYRIN LADDERS [J].