Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

被引：1779

作者：

Appel, Aaron M. ^{[1
]}

Bercaw, John E. ^{[2
]}

Bocarsly, Andrew B. ^{[3
]}

Dobbek, Holger ^{[4
]}

DuBois, Daniel L. ^{[1
]}

Dupuis, Michel ^{[1
]}

Ferry, James G. ^{[5
]}

Fujita, Etsuko ^{[6
]}

Hille, Russ ^{[7
]}

Kenis, Paul J. A. ^{[8
]}

Kerfeld, Cheal A. ^{[12
,13
]}

Morris, Robert H. ^{[14
]}

Peden, Charles H. F. ^{[1
]}

Portis, Archie R. ^{[9
,10
]}

Ragsdale, Stephen W. ^{[15
]}

Rauchfuss, Thomas B. ^{[11
]}

Reek, Joost N. H. ^{[16
]}

Seefeldt, Lance C. ^{[17
]}

Thauer, Rudolf K. ^{[18
]}

Waldrop, Grover L. ^{[19
]}

机构：

[1] Pacific NW Natl Lab, Inst Integrated Catalysis, POB 999, Richland, WA 99352 USA

[2] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[3] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

[4] Humboldt Univ, Inst Biol Strukturbiol Biochem, D-10099 Berlin, Germany

[5] Penn State Univ, Dept Biochem & Mol Biol, University Pk, PA 16801 USA

[6] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[7] Univ Calif Riverside, Dept Biochem, Riverside, CA 92521 USA

[8] Univ Illinois, Dept Chem & Biochem Engn, Urbana, IL 61801 USA

[9] Univ Illinois, Dept Crop Sci, Urbana, IL 61801 USA

[10] Univ Illinois, Dept Plant Biol, Urbana, IL 61801 USA

[11] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[12] DOE Joint Genome Inst, Walnut Creek, CA 94598 USA

[13] Univ Calif Berkeley, Dept Plant & Microbial Biol, Berkeley, CA 94720 USA

[14] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[15] Univ Michigan, Dept Biol Chem, Ann Arbor, MI 48109 USA

[16] Univ Amsterdam, vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

[17] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

[18] Max Planck Inst Terr Microbiol, D-35043 Marburg, Germany

[19] Louisiana State Univ, Dept Biol Sci, Baton Rouge, LA 70803 USA

来源：

CHEMICAL REVIEWS | 2013年 / 113卷 / 08期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; CARBON-MONOXIDE DEHYDROGENASE; CONTAINING FORMATE DEHYDROGENASE; COUPLED ELECTRON-TRANSFER; WOOD-LJUNGDAHL PATHWAY; COENZYME-A SYNTHASE; METAL-HYDRIDE BOND; ELECTROCHEMICAL REDUCTION; ACTIVE-SITE; ELECTROCATALYTIC REDUCTION;

D O I：

10.1021/cr300463y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The article discusses opportunities and challenges in biochemical and chemical catalysis of carbon dioxide fixation. All biological systems must extract energy from their environments to carry out the metabolic processes associated with life itself. Living organisms have evolved to exist in an amazing variety of environments, and they can use and interconvert energy from a variety of sources. The enzymes required to carry out these important metabolic pathways have evolved over billions of years, and they use readily abundant materials from the environment to achieve these important energy conversion processes. All of these metabolic pathways involve the storage and utilization of energy in the form of chemical bonds, and our ability to carry out these same transformations in a controlled and productive manner, independent of natural biological systems, will be critical to the future energy security.

引用

页码：6621 / 6658

页数：38

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