The pre-reactive complex H2O...ClF identified in mixtures of water vapour and chlorine monofluoride by rotational spectroscopy

被引：32

作者：

Cooke, SA

Cotti, G

Evans, CM

Holloway, JH

Legon, AC

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

[2] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 20期

关键词：

D O I：

10.1039/cc9960002327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A pre-reactive complex H2O ... ClF of planar (C-2 nu) or effectively planar (C-s) geometry is characterised for the first time in mixtures of water vapour and chlorine monofluoride through its rotational spectrum, as observed with a fast-mixing nozzle/Fourier-transform microwave spectrometer.

引用

页码：2327 / 2328

页数：2

共 17 条

[1] Is the gas-phase complex of ammonia and chlorine monofluoride H3N...ClF or [H3NCl](+)...F-? Evidence from rotational spectroscopy
Bloemink, HI
Evans, CM
Holloway, JH
Legon, AC
[J]. CHEMICAL PHYSICS LETTERS, 1996, 248 (3-4) : 260 - 268
[2] BOUGON R, 1967, CR ACAD SCI C CHIM, V265, P179
[3] REACTIONS OF CHLORINE FLUORIDES WITH HYDROXYL COMPOUNDS
CHRISTE, KO
[J]. INORGANIC CHEMISTRY, 1972, 11 (06) : 1220 - &
[4] MOLECULAR FORCE-FIELD AND STRUCTURE OF WATER - RECENT MICROWAVE RESULTS
COOK, RL
DELUCIA, FC
HELMINGER, P
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 53 (01) : 62 - 76
[5] MOLECULAR-BEAM ZEEMAN EFFECT AND DIPOLE-MOMENT SIGN OF CIF
FABRICANT, B
MUENTER, JS
[J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (12) : 5274 - 5277
[6] ROTATIONAL SPECTRUM AND PROPERTIES OF THE HYDROGEN-BONDED HETERODIMER H2O=HCN FROM PULSED-NOZZLE, FOURIER-TRANSFORM MICROWAVE SPECTROSCOPY
FILLERYTRAVIS, AJ
LEGON, AC
WILLOUGHBY, LC
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1984, 396 (1811): : 405 - 423
[7] Hinds K, 1996, MOL PHYS, V88, P673, DOI 10.1080/00268979609482446
[8] Legon A. C., 1988, FARADAY DISCUSS, V86, P269
[9] Legon A. C., 1992, ATOMIC MOL BEAM METH, V2, P289
[10] HYDROGEN-BONDING AS A PROBE OF ELECTRON-DENSITIES - LIMITING GAS-PHASE NUCLEOPHILICITIES AND ELECTROPHILICITIES OF B AND HX
LEGON, AC
MILLEN, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) : 356 - 358

← 1 2 →