Coordination of an imine ligand on an Os3 cluster stabilized by intramolecular Os-H---H-N hydrogen bonding

被引：28

作者：

Aime, S ^{[1
]}

Férriz, M ^{[1
]}

Gobetto, R ^{[1
]}

Valls, E ^{[1
]}

机构：

[1] Univ Turin, Dipartimento Chim Inorgan Chim Fis & Chim Mat, I-10125 Turin, Italy

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 10期

关键词：

D O I：

10.1021/om980885b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of CH3CHO to a chloroform solution of H(mu-H)Os-3(CO)(10)(NH3) affords the new H(mu-H)Os-3(CO)(10)(HN=CHCH3) derivative where the imine ligand occupies a terminal position. The stereochemistry of the adduct appears to be determined by the occurrence of an unconventional hydrogen-bond interaction involving the N-H moiety and the terminal hydride.

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页码：2030 / 2032

页数：3

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