The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

被引：66

作者：

Anastasaki, Athina ^{[1
]}

Waldron, Christopher ^{[1
]}

Wilson, Paul ^{[1
]}

McHale, Ronan ^{[1
]}

Haddleton, David M. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 09期

关键词：

SET-LRP; METHYL ACRYLATE; MULTIBLOCK COPOLYMERS; SOLVENT; DISPROPORTIONATION; CU(0); ATRP; METHACRYLATES; 25-DEGREES-C; COMPLEXES;

D O I：

10.1039/c3py00270e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me(6)Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

引用

页码：2672 / 2675

页数：4

共 38 条

[1] Copper(0)- mediated radical polymerisation in a self-generating biphasic system [J].

Boyer, Cyrille ;

Atme, Amir ;

Waldron, Christopher ;

Anastasaki, Athina ;

Wilson, Paul ;

Zetterlund, Per B. ;

Haddleton, David ;

Whittaker, Michael R. .

POLYMER CHEMISTRY, 2013, 4 (01) :106-112

[2] Synthesis of multi-block copolymer stars using a simple iterative Cu(0)-mediated radical polymerization technique [J].

Boyer, Cyrille ;

Derveaux, Aurelia ;

Zetterlund, Per B. ;

Whittaker, Michael R. .

POLYMER CHEMISTRY, 2012, 3 (01) :117-123

[3] Synthesis of Complex Multiblock Copolymers via a Simple Iterative Cu(0)-Mediated Radical Polymerization Approach [J].

Boyer, Cyrille ;

Soeriyadi, Alexander H. ;

Zetterlund, Per B. ;

Whittaker, Michael R. .

MACROMOLECULES, 2011, 44 (20) :8028-8033

[4] New insights into the mechanism of activation of atom transfer radical polymerization by Cu(I) complexes [J].

De Paoli, Patrizia ;

Isse, Abdirisak A. ;

Bortolamei, Nicola ;

Gennaro, Armando .

CHEMICAL COMMUNICATIONS, 2011, 47 (12) :3580-3582

[5] The persistent radical effect: A principle for selective radical reactions and living radical polymerizations [J].

Fischer, H .

CHEMICAL REVIEWS, 2001, 101 (12) :3581-3610

[6]

Fischer H, 1999, J POLYM SCI POL CHEM, V37, P1885, DOI 10.1002/(SICI)1099-0518(19990701)37:13<1885::AID-POLA1>3.3.CO

[7]

2-T

[8] Atom transfer radical polymerisation (ATRP) of methyl methacrylate in the presence of radical inhibitors [J].

Haddleton, DM ;

Clark, AJ ;

Crossman, MC ;

Duncalf, DJ ;

Heming, AM ;

Morsley, SR ;

Shooter, AJ .

CHEMICAL COMMUNICATIONS, 1997, (13) :1173-1174

[9] Cooperative and Synergistic Solvent Effects in SET-LRP of MA [J].

Jiang, Xuan ;

Fleischmann, Sven ;

Nguyen, Nga H. ;

Rosen, Brad M. ;

Percec, Virgil .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (21) :5591-5605

[10] Visualization of the crucial step in SET-LRP [J].

Levere, Martin E. ;

Nguyen, Nga H. ;

Leng, Xuefei ;

Percec, Virgil .

POLYMER CHEMISTRY, 2013, 4 (05) :1635-1647

← 1 2 3 4 →