Effect of composition on dielectric and electrical properties of the Sr1-xLaxTi1-xCoxO3 system

被引:90
作者
Upadhyay, S
Kumar, D
Parkash, O
机构
[1] BANARAS HINDU UNIV,INST TECHNOL,SCH MAT SCI & TECHNOL,VARANASI 221005,UTTAR PRADESH,INDIA
[2] BANARAS HINDU UNIV,INST TECHNOL,DEPT CERAM ENGN,VARANASI 221005,UTTAR PRADESH,INDIA
关键词
dielectric properties; relaxor; impedance and modulus spectroscopy;
D O I
10.1007/BF02744823
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Valence compensated perovskite system Sr1-xLaxTi1-xCoxO3 shows dielectric relaxer behaviour with very high value of dielectric constant in the composition range 0.20 < x < 0.40. In this paper the effect of composition on microstructure and the resulting electrical behaviour is reported. The composition's with x = 0.25, 0.30, 0.33, 0.35 and 0.37 have been synthesized by solid state ceramic method and dielectric measurements were made in the temperature range of 300-500 K and frequency range of 100 Hz to 1 MHz Grain boundaries played an important role in their dielectric behaviour. Complex plane impedance and modulus techniques were used to separate out the contributions of grain and grain-boundaries to the resulting dielectric behaviour. It was observed that the bulk resistivity as well as the grain boundaries resistance decreased with increasing x. Furthermore, impedance analysis demonstrated that extremely high value of dielectric constant observed in these materials was due to barrier layers formation at grain-grain-boundaries interfaces.
引用
收藏
页码:513 / 525
页数:13
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