Investigation into the effect of ultrasound on the dimerization of pivalic acid using Fenton's reagent

被引:11
作者
Bremner, DH [1 ]
Mitchell, SR [1 ]
Staines, H [1 ]
机构
[1] UNIV ABERTAY DUNDEE,DEPT MATH & COMP SCI,DUNDEE DD1 1HG,SCOTLAND
关键词
ultrasound; hydroxyl radicals; pivalic acid; dimerization; analysis of variance;
D O I
10.1016/1350-4177(95)00035-6
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
The effect of ultrasound on the dimerization of pivalic acid using Fenton's reagent to generate hydroxyl radicals was investigated. The results of varying several experimental conditions were analysed using statistical techniques. Yields of tetramethyladipic acid depend greatly on the gas saturating the solution. For nitrogen, the optimal combination is 0.17 equivalents of Fenton's reagent, high dilution and no ultrasound.
引用
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页码:47 / 52
页数:6
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