A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3

被引：35

作者：

Chandrasekhar, S ^{[1
]}

Chandrashekar, G ^{[1
]}

Reddy, MS ^{[1
]}

Srihari, P ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2006年 / 4卷 / 09期

关键词：

D O I：

10.1039/b603610b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly chemoselective conjugate reduction of electron-deficient Michael acceptors, including alpha,beta-unsaturated ketones, carboxylic esters, nitriles and nitro compounds with PMHS in the presence of catalytic B(C6F5)(3) is described.

引用

页码：1650 / 1652

页数：3

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