Synthesis of stars and starlike block copolymers from a trialkoxyamine used as initiator

被引：36

作者：

Robin, S

Guerret, O

Couturier, JL

Gnanou, Y

机构：

[1] Univ Bordeaux 1, ENSCPB, CNRS, Lab Chim Polymeres Organ, F-33402 Talence, France

[2] ATOFINA, Ctr Rech Rhone Alpes, F-69310 Pierre Benite, France

来源：

MACROMOLECULES | 2002年 / 35卷 / 07期

关键词：

D O I：

10.1021/ma011261b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This study investigates the efficiency of a novel trifunctional alkoxyamine (1) based on N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (SG1) (2) as initiator for the controlled radical polymerization of styrene (S) and n-butyl acrylate (nBuA). Three factors, namely the concentration of SG1 initially introduced in excess, the monomer conversion, and-in the specific case of PS samples the monomer autopolymerization, were found to control the quality of the star samples obtained. Well-defined T-(PBuA-b-PS)(3) star block copolymers could also be synthesized by sequential copolymerization using the same trifunctional initiator.

引用

页码：2481 / 2486

页数：6

共 30 条

[1]

[Anonymous], 2000, ACS SYM SER, DOI [DOI 10.1021/BK-2000-0768.CH008, 10.1021/bk-2000-0768.ch008]

[2]

[Anonymous], ACS S SERIES

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