Photochemistry and photoinduced chemical crosslinking activity of type I & II co-reactive photoinitiators in acrylated prepolymers

The photoreactivity of Type I and II photointiators, namely, 4-(2-hydroxyethoxy)-phenyl-(2-hydroxy2-methylpropyl) ketone (Irgacure 2959, Ciba-Geigy) and 4-hydroxybenzophenone, respectively, have been examined in the free and bound form in melamine and urethane acrylate prepolymers. Go-reaction in the prepolymers was undertaken by partial replacement of the hydroxyacrylate components with the photoinitiators in the reaction with the isocyanate component. Both the photoinitiators were also converted into their corresponding acrylate derivatives for study. The free, bound and acrylated derivatives were then analysed by various spectroscopic techniques to evaluate the relationship between their photophysical properties and photoinitiation activity for photocrosslinking of commercial acrylated monomers and prepolymers. Photocuring studies using Hg sources (conveyor and RTIR) indicated that whilst binding the Type I photointiator reduced its efficiency in cure, the Type II photoinitiator was enhanced. The presence of an amine co-synergist, however, generally eliminated these differentials. Acrylation of the Irgacure 2959 also reduced photoactivity. Absorption spectroscopy indicated the presence of a strongly absorbing n pi* transition in the far UV region for both chromophore types which undergoes a blue shift on binding to the prepolymer. Phosphorescence spectra, lifetimes and quantum yields also indicate the presence of low lying triplet n pi* states for both types of chromophore. Binding appears to enhance the triplet Lifetime and reduce the quantum yield of emission due to increased electron donation into the chromophore by the resin component and may in part account for their lower photoactivity. Microsecond flash photolysis identified the formation of benzoyl radicals in the case of the Type I system with a small enhancement in radical formation on binding. The Type IT system gave ketyl radicals formed by hydrogen atom abstraction which were enhanced in the bound resin system. The latter would account for increased photoactivity for the bound Type II system. Nanosecond laser flash photolysis experiments identified the triplet-triplet absorption in the case of the Type II initiator. In the presence of a tertiary amine (triethylamine) the transient absorption and its Lifetime were significantly enhanced due to exciplex formation. However, binding the benzophenone initiator to the resin significantly quenched the transient absorption and significantly reduced its lifetime. In the case of the Type I initiator the benzoyl radical was observed directly, confirming the microsecond flash photolysis data. Binding of the initiator to the melamine acrylate resin also reduced benzoyl radical formation and reduced the radical lifetime. This may account for the reduced photoactivity of the Type I bound initiator. Radical formation was also reduced when bound to the urethane acrylate but the lifetime was enhanced. For the initiator bound resin systems the presence of an amine co-synergist enhanced benzoyl radical formation. The implications of initiator co-reactions are discussed in terms of both the photochemical and commercial benefits. (C) 1999 Elsevier Science S.A. All rights reserved.