Electro-organic synthesis of thioether and benzofuran derivatives

被引:7
作者
Davarani, Saied Saeed Hosseiny [1 ]
Ramyar, Somayyeh [1 ]
Masoumi, Leila [1 ]
Fumani, Neda Sheijooni [1 ]
Moghaddam, Abdolmajid Bayandori [2 ]
机构
[1] Shahid Beheshti Univ Med Sci, Fac Sci, Dept Chem, Tehran 1983963113, Iran
[2] Univ Tehran, Med Nanotechnol Res Ctr, Tehran, Iran
关键词
D O I
10.1149/1.2948383
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electro-oxidation of 2,3-dimethylhydroquinone (1) has been studied in the presence of 2-hydroxy-1,4-naphthoquinone (4a), 2-mercaptobenzothiazole (3b), 2-mercaptobenzoxazole (3c), and thiazoline-2-thiol (3d) in aqueous solution, using cyclic voltammetry and controlled-potential coulometry. The results indicate that p-benzoquinone, generated by the electrochemical oxidation of 2,3-dimethylhydroquinone, is scavenged by 4a and 3b-3d to give the related products 7a, 5b-5d via various electrochemical mechanisms. (C) 2008 The Electrochemical Society.
引用
收藏
页码:E120 / E124
页数:5
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