Bis(amido)magnesium mediated aldol additions: first structural characterisation of an amidomagnesium aldolate intermediate

被引：42

作者：

Allan, JF ^{[1
]}

Henderson, KW ^{[1
]}

Kennedy, AR ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 14期

关键词：

D O I：

10.1039/a903784e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(hexamethyldisilazido)magnesium has successfully been used to mediate aldol additions of selected ketones and aldehydes in hydrocarbon media, and the structure of an intermediate amido(aldolate), [{(Me3Si)(2)NMg[mu-OC(Me)(BuCH2C)-C-t(Bu-t)=O]}(2)] 17, produced by the self-coupled reaction of pinacolone has been characterised by X-ray crystallography.

引用

页码：1325 / 1326

页数：2

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