Low temperature Fischer-Tropsch synthesis from a Sasol perspective

被引:206
作者
Espinoza, RL [1 ]
Steynberg, AP [1 ]
Jager, B [1 ]
Vosloo, AC [1 ]
机构
[1] Sasol Technol Res & Dev Div, ZA-9570 Sasolburg, South Africa
关键词
D O I
10.1016/S0926-860X(99)00161-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The characteristics of a slurry phase reactor are contrasted with those of a conventional tubular fixed bed reactor (TFBR) for the conversion of synthesis gas to long chain hydrocarbons. Hydrodynamic information needed for the design of a commercial scale slurry phase Fischer-Tropsch (FT) reactor were obtained from experiments carried out on a 1 m internal diameter pilot plant reactor. The kinetics, selectivities and deactivation mechanisms of Fe and supported Co FT catalysts are compared for both slurry phase and fixed bed operation. The combined advantages of the slurry phase reactor and a very active Co catalyst create the opportunity to convert remote natural gas to high quality middle distillates in a cost effective manner. (C)1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:13 / 26
页数:14
相关论文
共 39 条
[1]  
[Anonymous], GER CHEM ENG
[2]  
[Anonymous], 1981, CATALYSIS SCI TECHNO
[3]   KINETICS OF FISCHER-TROPSCH REACTION OVER IRON [J].
ATWOOD, HE ;
BENNETT, CO .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1979, 18 (01) :163-170
[4]  
BROTZ WZ, 1946, ELEKTROCHEMISTRY, V5, P301
[5]  
DARTON RC, 1977, T I CHEM ENG-LOND, V55, P274
[6]  
Deckwer W. D., 1992, BUBBLE COLUMN REACTO
[7]   ADVANCES IN FISCHER-TROPSCH CHEMISTRY [J].
DRY, ME .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1976, 15 (04) :282-286
[8]  
DRY ME, 1982, HYDROCARB PROCESS, V61, P124
[9]  
DUVENHAGE D, 1994, STUD SURF SCI CATAL, V88, P3501
[10]   A unified approach to the scale-up of gas-solid fluidized bed and gas-liquid bubble column reactors [J].
Ellenberger, J. ;
Krishna, R. .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (24B) :5391-5411