New self-assembly luminescent molecular triangle and square Rhenium(I) complexes

被引：97

作者：

Sun, SS ^{[1
]}

Lees, AJ ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 19期

关键词：

D O I：

10.1021/ic990129d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two luminescent triangle and square complexes with the general formulas [ClRe(CO)(3)(mu-DPB)](4) (1) and [BrRe(CO)(3)(mu-BPDB)](3) (2), where DPB = 4,4'-dipyridylbutadiyne and BPDB = 1,4-bis(4'-pyridylethynyl)-2,5-dihexyloxybenzene, were prepared by self-assembly reactions of XRe(CO)(5) (X = Cl or Br) and the corresponding bis-monodentate ligands. The structures of these molecules were confirmed by a variety of techniques including NMR spectroscopy, IR spectroscopy, FAB(+) mass spectrometry, and elemental analysis.

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页码：4181 / +

页数：3

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