Properties of electroless Ni-P deposition of glass substrates using a mercapto organosilanes for functional groups to graft palladium

被引：8

作者：

Chi, F. T. ^{[1
,2
]}

Jiang, K. ^{[1
,2
]}

Li, B. ^{[1
]}

Jiang, B. ^{[2
]}

机构：

[1] China Acad Engn Phys, Res Ctr Laser Fus, Mianyang 621900, Peoples R China

[2] Sichuan Univ, Coll Chem, Chengdu 614004, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2008年 / 255卷 / 05期

关键词：

Self-assembled monolayer (SAM) films; Ni-P deposits; gamma-Mercaptopropyltrimethoxysilane; XPS; Nanoindentation;

D O I：

10.1016/j.apsusc.2008.08.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A gamma-mercaptopropyltrimethoxysilane (gamma-MPS) conversion film was proposed as the pretreatment between Ni-P deposits and glass substrate to graft palladium onto sulfur atom replacing conventional amine functional groups. The subsequent Ni-P deposit was characterized by its chemical state, morphology, thermodynamics and nanoindentation analysis. Different thermal treatments of the pretreated deposit obtained different chemical state of Ni element. The crystallization and phase transformation behavior of electroless Ni-P deposits during thermal treatment have a vital role in determining their properties, such as hardness, elastic modulus, and so on, which were studied by nanoindentation technology. (C) 2008 Elsevier B. V. All rights reserved.

引用

页码：2740 / 2745

页数：6

共 21 条

[1] Electronic structure of nanostructured nickel oxide using Ni 2p XPS analysis [J].

Biju, V ;

Khadar, MA .

JOURNAL OF NANOPARTICLE RESEARCH, 2002, 4 (03) :247-253

[2]

BRANDRETH DA, 1972, NATURE-PHYS SCI, V11, P2369

[3] Ni direct electroless metallization of polymers by a new palladium-free process [J].

Charbonnier, M ;

Romand, M ;

Goepfert, Y .

SURFACE & COATINGS TECHNOLOGY, 2006, 200 (16-17) :5028-5036

[4] Copper metallization of polymers by a palladium-free electroless process [J].

Charbonnier, M ;

Romand, M ;

Goepfert, Y ;

Léonard, D ;

Bouadi, M .

SURFACE & COATINGS TECHNOLOGY, 2006, 200 (18-19) :5478-5486

[5]

Charbonnier M, 2004, 14TH CONGRESS OF INTERNATIONAL FEDERATION FOR HEAT TREATMENT AND SURFACE ENGINEERING, VOLS 1 AND 2, PROCEEDINGS, P1106

[6] Polymer pretreatments for enhanced adhesion of metals deposited by the electroless process [J].

Charbonnier, M ;

Romand, M .

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2003, 23 (04) :277-285

[7] Tin-free electroless metallization of glass substrates using different PACVD surface treatment processes [J].

Charbonnier, M ;

Romand, M .

SURFACE & COATINGS TECHNOLOGY, 2003, 162 (01) :19-30

[8] Electroless plating of polymers: XPS study of the initiation mechanisms [J].

Charbonnier, M ;

Alami, M ;

Romand, M .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1998, 28 (04) :449-453

[9] Equilibrium study on Pd(II) chelates of mercapto carboxylic acids [J].

Crisponi, G ;

Cristiani, F ;

Nurchi, VM ;

Pinna, R ;

Estévez, MJT .

POLYHEDRON, 1999, 18 (25) :3257-3262

[10] Physics of contact angle measurement [J].

Decker, EL ;

Frank, B ;

Suo, Y ;

Garoff, S .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 156 (1-3) :177-189

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