Gas phase hydrogen-bonded complexes of aromatic molecules: photoionization and energetics

被引:62
作者
Mons, M [1 ]
Dimicoli, I [1 ]
Piuzzi, F [1 ]
机构
[1] CEA, CNRS, FRE 2298,Ctr Etud Saclay, Lab Francis Perrin,Serv Photons Atomes & Mol, F-91191 Gif Sur Yvette, France
关键词
D O I
10.1080/01442350110104310
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present review discusses the possibility of measuring the dissociation energy of gas phase complexes from their dissociative photoionization. A compilation of recent results on hydrogen-bonded complexes of aromatic molecules, with a polar solvent molecule (water, alcohol, NH3, HCl, etc.), playing the role of either proton donor or proton acceptor is presented. We show that laser experiments begin to provide a consistent set of energetic data that can be considered as benchmarks to assess quantum calculations as well as to parametrize the force field models used in biochemistry.
引用
收藏
页码:101 / 135
页数:35
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