Polyaniline nanowires by electropolymerization from liquid crystalline phases

被引：201

作者：

Huang, LM ^{[1
]}

Wang, ZB ^{[1
]}

Wang, HT ^{[1
]}

Cheng, XL ^{[1
]}

Mitra, A ^{[1
]}

Yan, YS ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem & Environm Engn, Riverside, CA 92521 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 02期

关键词：

D O I：

10.1039/b107499g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conductive polyaniline nanowires in emeraldine form can be deposited by potentiodynamic electropolymerization from a reverse hexagonal liquid crystalline phase where one-dimensional (1D) aqueous channels can serve as space-confined reactors. Polyaniline nanowire bundles with single-wire diameter of 50-70 nm and length of several microns were obtained from surfactant sodium bis(2-ethylhexyl) sulfosuccinate (AOT) reverse hexagonal liquid crystalline phase. Impedance measurement suggests improved ordering of the reverse hexagonal liquid crystal under external electric field during the electropolymerization process. This enhanced ordering appears essential for the nanowire growth. The nanowires obtained can be easily collected by a simple washing process.

引用

页码：388 / 391

页数：4

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