Electrocatalytic and Photocatalytic Hydrogen Production in Aqueous Solution by a Molecular Cobalt Complex

被引：271

作者：

Singh, Wangkheimayum Marjit ^{[1
]}

Baine, Teera ^{[1
]}

Kudo, Shotaro ^{[1
]}

Tian, Shiliang ^{[2
,3
]}

Ma, Xuan Anh N. ^{[1
]}

Zhou, Hongyu ^{[2
]}

DeYonker, Nathan J. ^{[1
]}

Truc Chi Pham ^{[1
]}

Bollinger, John C. ^{[2
]}

Baker, Daniel L. ^{[1
]}

Yan, Bing ^{[2
]}

Webster, Charles Edwin ^{[1
]}

Zhao, Xuan ^{[1
]}

机构：

[1] Memphis State Univ, Dept Chem, Memphis, TN 38152 USA

[2] St Jude Childrens Res Hosp, Dept Chem Biol & Therapeut, Memphis, TN 38105 USA

[3] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 24期

基金：

美国国家科学基金会;

关键词：

cobalt; electrocatalysis; homogeneous catalysis; hydrogen; photochemistry; H-2; PRODUCTION; GENERATING HYDROGEN; FUNCTIONAL MODELS; WATER REDUCTION; VISIBLE-LIGHT; ACTIVE-SITE; EVOLUTION; CATALYSTS; SYSTEM; COBALOXIMES;

D O I：

10.1002/anie.201200082

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mononuclear cobalt complex supported by a new type of pentadentate ligand catalyzed the evolution of hydrogen in purely aqueous solution (see picture). This cobalt complex could serve as both electrocatalyst and photocatalyst for efficient evolution of hydrogen. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5941 / 5944

页数：4

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