Synthesis, characterization and structure of ferrocenylketimine complexes of platinum(II)

被引：45

作者：

Wu, YJ ^{[1
]}

Ding, L ^{[1
]}

Wang, HX ^{[1
]}

Liu, YH ^{[1
]}

Yuan, HZ ^{[1
]}

Mao, XA ^{[1
]}

机构：

[1] CHINESE ACAD SCI,WUHAN INST PHYS,LAB MAGNET RESONANCE & ATOM & MOL PHYS,WUHAN 340071,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 535卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

ferrocene; platinum; cyclometallation; crystal structure; CYCLOMETALATED COMPLEXES; PALLADIUM(II); METALS; ALKYL;

D O I：

10.1016/S0022-328X(96)06948-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of ferrocenylketimines [(eta(5)-C5H4CMe=NAr)Fe(eta(5)-C5H5)] (Ar=a variety of substituted phenyls) with cis-Pt(DMSO)(2)Cl-2 in refluxing toluene have led to the formation of both the five-membered cycloplatinated derivatives [sigma-Pt{(eta(5)-C5H4CMe=NAr)Fe(eta(5)-C5H5)}(DMSO)Cl] in the presence of sodium acetate and the coordinated compounds [trans-PtCl2(DMSO){(eta(5)-C5H4CMe=NAr)Fe(eta(5)-C5H5)}] in the absence of sodium acetate. The compounds have been characterized by elemental analysis, IR, H-1 NMR and two-dimensional NOESY spectra. The X-ray crystal structures of [sigma-Pt{(eta(5)-C5H3CMe=NPh)Fe(eta(5)-C5H5)}(DMSO)Cl] and [trans-PtCl2(DMSO){(eta(5)-C5H4CMe=NPh)Fe(eta(5)-C5H5)}] have been determined. (C) 1997 Elsevier Science S.A

引用

页码：49 / 58

页数：10

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