Preparation and characterization of hybrid organic-inorganic composite materials using the amphoteric property of amino acids:: Amino acid intercalated layered double hydroxide and montmorillonite

被引:127
作者
Fudala, A
Pálinkó, I
Kiricsi, I
机构
[1] Attila Jozsef Univ, Dept Organ Chem, H-6720 Szeged, Hungary
[2] Attila Jozsef Univ, Dept Appl Chem, H-6720 Szeged, Hungary
基金
美国国家科学基金会;
关键词
D O I
10.1021/ic981176t
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Deprotonated and protonated forms of L-tyrosine or L-phenylalanine were intercalated by Zn-Al hydrotalcite (HT) and Na-montmorillonite (Na-mont), respectively. The intercalated materials were characterized by powder X-ray diffraction, BET measurements, and FT-IR spectroscopy. Intercalation was successful as the increased basal spacings attested. For hydrotalcite this increase was always significantly larger than for montmorillonite. This fact indicated that the spatial arrangement of the amino acid moieties was very different. A model for this arrangement has been suggested. A variety of methods showed that L-Tyr(Phe)-HT was thermally less stable than HT, while the heat resistance of L-Tyr(Phe)-mont did not change.
引用
收藏
页码:4653 / 4658
页数:6
相关论文
共 14 条
[1]   Synthesis and characterization of polyoxovanadate-pillared Zn-Al layered double hydroxides: An x-ray absorption and diffraction study [J].
Barriga, C ;
Jones, W ;
Malet, P ;
Rives, V ;
Ulibarri, MA .
INORGANIC CHEMISTRY, 1998, 37 (08) :1812-1820
[2]  
BURCH R, 1987, CATAL TODAY, V2, P185
[3]   The intercalation of carboxylic acids into layered double hydroxides: A critical evaluation and review of the different methods [J].
Carlino, S .
SOLID STATE IONICS, 1997, 98 (1-2) :73-84
[4]  
De Roy A., 1992, SYNTHESIS MICROPOROU, V2, P108
[5]   THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].
DEWAR, MJS ;
ZOEBISCH, EG ;
HEALY, EF ;
STEWART, JJP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909
[6]  
*HYP INC, 1994, HYP 4 5
[7]  
IZUMI Y, 1992, ZEOLITE CLAY HETEROP, P53
[8]  
Jones W., 1991, PILLARED LAYER STRUC, P67
[9]   Preferential intercalation of isomers of anthraquinone sulfonate ions into layered double hydroxides [J].
Kuk, WK ;
Huh, YD .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (09) :1933-1936
[10]  
NEMECZ E, 1981, CLAY MINER, P170