Liquid phase oxidation of alkenes with nitrous oxide to carbonyl compounds

被引：51

作者：

Starokon, EV ^{[1
]}

Dubkov, KA ^{[1
]}

Babushkin, DE ^{[1
]}

Parmon, VN ^{[1
]}

Panov, GI ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 2-3期

关键词：

alkenes oxidation; carbene; carbonyl compounds; cycloheptatriene; cyclopropane; methylene; nitrous oxide;

D O I：

10.1002/adsc.200303155

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A variety of substrates including linear, cyclic, heterocyclic alkenes and their derivatives were tested in the liquid phase non-catalytic oxidation with nitrous oxide (N2O). The structure and composition of the alkenes have a significant effect on the reaction selectivity. With many alkenes, N2O oxidation provides a selective way for the preparation of carbonyl compounds. The generation of carbene (or diazomethane) species is a remarkable feature of the oxidation of terminal alkenes.

引用

页码：268 / 274

页数：7

共 18 条

[1] Mechanism of direct oxidation of cyclohexene to cyclohexanone with nitrous oxide. Theoretical analysis by DFT method [J].

Avdeev, VI ;

Ruzankin, SP ;

Zhidomirov, GM .

CHEMICAL COMMUNICATIONS, 2003, (01) :42-43

[2]

BRANDT BB, 1960, KHIM PROMST, V5, P67

[3] OXIDATION OF ORGANIC COMPOUNDS BY NITROUS OXIDE .2. TRI-SUBSTITUTED AND TETRA-SUBSTITUTED ETHYLENES [J].

BRIDSONJONES, FS ;

BUCKLEY, GD .

JOURNAL OF THE CHEMICAL SOCIETY, 1951, (NOV) :3009-3016

[4] OXIDATION OF ORGANIC COMPOUNDS BY NITROUS OXIDE .1. [J].

BRIDSONJONES, FS ;

BUCKLEY, GD ;

CROSS, LH ;

DRIVER, AP .

JOURNAL OF THE CHEMICAL SOCIETY, 1951, (NOV) :2999-3008

[5]

Centi G, 1999, CHEMTECH, V29, P48

[6] Non-catalytic liquid phase oxidation of alkenes with nitrous oxide. 2. Oxidation of cyclopentene to cyclopentanone [J].

Dubkov, KA ;

Panov, GI ;

Starokon, EV ;

Parmon, VN .

REACTION KINETICS AND CATALYSIS LETTERS, 2002, 77 (01) :197-205

[7]

KIRMSE W, 1964, CARBENE CHEMISTRY, pCH2

[8]

Leont'ev AV, 2001, USP KHIM+, V70, P107

[9] Ammonia oxidation into nitrous oxide over Mn/Bi/Al catalyst I. Single cooling tube experiments [J].

Noskov, AS ;

Zolotarskii, IA ;

Pokrovskaya, SA ;

Korotkikh, VN ;

Slavinskaya, EM ;

Mokrinskii, VV ;

Kashkin, VN .

CHEMICAL ENGINEERING JOURNAL, 2003, 91 (2-3) :235-242

[10]

PANETIER G, 1955, P 5 S COMB, P620

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