Design of chiral tin(IV) aryloxide as a mild Lewis acid catalyst for enantioselective Diels-Alder reaction

被引：7

作者：

Kano, T ^{[1
]}

Konishi, T ^{[1
]}

Konishi, S ^{[1
]}

Maruoka, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 06期

关键词：

asymmetric catalysis; Lewis acids; Sn; Diels-Alder reaction;

D O I：

10.1016/j.tetlet.2005.12.001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel Sn(IV) aryloxide Lewis acid has been designed and prepared from SnCl4 and (S)-3,3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol. The chiral Sn(IV) Lewis acid has been successfully applied to the enantioselective Diels-Alder reaction. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：873 / 875

页数：3

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