Rapid fabrication of three-dimensional porous films with biomimetic patterns by natural evaporation of amphiphilic polyacetylene solutions under ambient conditions

被引：17

作者：

Salhi, F ^{[1
]}

Cheuk, KKL ^{[1
]}

Sun, QH ^{[1
]}

Lam, JWY ^{[1
]}

Cha, JAK ^{[1
]}

Li, G ^{[1
]}

Li, BS ^{[1
]}

Luo, JD ^{[1
]}

Chen, JW ^{[1
]}

Tang, BZ ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Inst Nano Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2001年 / 1卷 / 02期

关键词：

amphiphilic macromolecules; substituted polyacetylenes; self-organization; polymer vesicles; porous thin films; biomimetic morphology; honeycomb-like pattern;

D O I：

10.1166/jnn.2001.022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple process for fast fabrication of thin films with biomimetic morphological structures from a group of linear homopolymers is developed. Natural evaporation of tetrahydrofuran, chloroform, and hexane-dichloromethane solutions of poly(phenylacetylene)s that contain amino acid and ethylene glycol moieties under ambient conditions instantly produces three-dimensional porous films with structural patterns reminiscent of honeycombs and radiolarian shells. Morphological analysis by optical and electronic microscopy suggests that vesicles of the amphiphilic polymers serve as building blocks in the self-organization to the biomimetic structures.

引用

页码：137 / 141

页数：5

共 43 条

[1]

Alexandridis P., 2000, AMPHIPHILIC BLOCK CO

[2]

[Anonymous], POLYM MAT SCI ENG

[3]

Brinker CJ, 1999, ADV MATER, V11, P579, DOI 10.1002/(SICI)1521-4095(199905)11:7<579::AID-ADMA579>3.0.CO

[4]

2-R