Noncovalent π•••π-stacked exo-functional nanotubes:: Subtle control of resorcinarene self-assembly

被引：114

作者：

Mansikkamäki, H ^{[1
]}

Nissinen, M ^{[1
]}

Rissanen, K ^{[1
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, Nanosci Ctr, Jyvaskyla 40014, Finland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期

关键词：

crystal engineering; host-guest systems; nanotubes; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200353112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By manipulating the crystallization conditions of C-methyl recorcinarene, a motif of self-assembled helical nanotubes held together by extensive π⋯π interactions is obtained. The tube, depicted (red = O, white = H, gray = C), has an exo-functionalized hydrophilic outer surface capable of complex formation with cationic or neutral guests and a hydrophobic interior potentially suitable for the transportation of small hydrophobic molecules.

引用

页码：1243 / 1246

页数：4

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