Evolution of electronic structure and spectral evaluation in single-crystal Mn3O4 nanorods

被引：14

作者：

Chen, Zhiwen ^{[1
]}

Lai, Joseph K. L. ^{[1
]}

Shek, Chan-Hung ^{[1
]}

机构：

[1] City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China

来源：

JOURNAL OF CHEMICAL PHYSICS | 2006年 / 124卷 / 18期

关键词：

D O I：

10.1063/1.2199848

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single-crystal Mn3O4 nanorods with tetragonal structure have been successfully prepared by a chemical reaction route. Transmission electron microscopy (TEM) and high-resolution TEM studies prove that the single-crystal Mn3O4 nanorod is smooth and straight, and that the geometrical shape is structurally perfect. We investigated the electronic characteristics of Mn3O4 nanorods by various spectral evaluations. The present study confirms that the hybridization between oxygen 2p and manganese 3d orbits plays an important role when considering electronic structures of Mn3O4 nanorods. (c) 2006 American Institute of Physics.

引用

页数：5

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