Development and testing of anode-supported solid oxide fuel cells with slurry-coated electrolyte and cathode

被引:28
作者
Muccillo, R.
Muccillo, E. N. S.
Fonseca, F. C.
Franca, Y. V.
Porfirio, T. C.
de Florio, D. Z.
Berton, M. A. C.
Garcia, C. M.
机构
[1] IPEN, Ctr Ciencia & Tecnol Mat, BR-05422970 Sao Paulo, Brazil
[2] UNESP, Inst Quim, BR-14801970 Araraquara, SP, Brazil
[3] DPMA, Inst Tecnol Desenvolvimento, BR-81531980 Curitiba, Parana, Brazil
基金
巴西圣保罗研究基金会;
关键词
solid oxide fuel cells; solid electrolyte; anode; cathode; impedance spectroscopy;
D O I
10.1016/j.jpowsour.2005.06.021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A laboratory setup was designed and put into operation for the development of solid oxide fuel cells (SOFCs). The whole project consisted of the preparation of the component materials: anode, cathode and electrolyte, and the buildup of a hydrogen leaking-free sample chamber with platinum leads and current collectors for measuring the electrochemical properties of single SOFCs. Several anode-supported single SOFCs of the type (ZrO2:Y2O3+NiO) thick anode/(ZrO2:Y2O3) thin electrolyte/(La0.65Sr0.35MnO3+ZrO2:Y2O3) thin cathode have been prepared and tested at 700 and 800 degrees C after in situ H-2 anode reduction. The main results show that the slurry-coating method resulted in single-cells with good reproducibility and reasonable performance, suggesting that this method can be considered for fabrication of SOFCs. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:455 / 460
页数:6
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