Synthesis of aluminate polymer complexes as single-ionic solid electrolytes

被引：53

作者：

Onishi, K ^{[1
]}

Matsumoto, M ^{[1
]}

Nakacho, Y ^{[1
]}

Shigehara, K ^{[1
]}

机构：

[1] TOKYO UNIV AGR & TECHNOL, GRAD SCH BIOAPPLICAT & SYST ENGN, KOGANEI, TOKYO 184, JAPAN

来源：

CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 02期

关键词：

D O I：

10.1021/cm950388a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Main-chain anionic polymers with lithium cations, which have oligo(oxyethylene)aluminate chain backbones attached with two side chains of endo-methoxy[oligo(oxyethylene)], were prepared, and their ionic conductivities are reported. The ac conductivity of aluminate polymer complex was about 10(-6)-10(-7) S cm(-)11 at room temperature. As the constant current was observed for [Li/aluminate polymer complex/Li] cells under de electric field, the single-ionic conduction was confirmed.

引用

页码：469 / 472

页数：4

共 11 条

[1] THE REACTION OF LITHIUM ALUMINUM HYDRIDE WITH ALCOHOLS - LITHIUM TRI-TERT-BUTOXY-ALUMINOHYDRIDE AS A NEW SELECTIVE REDUCING AGENT [J].

BROWN, HC ;

MCFARLIN, RF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (20) :5372-5376

[2] SYNTHESIS AND ELECTRICAL RESPONSE OF SINGLE-ION CONDUCTING NETWORK POLYMERS BASED ON SODIUM POLY(TETRAALKOXYALUMINATES) [J].

DOAN, KE ;

RATNER, MA ;

SHRIVER, DF .

CHEMISTRY OF MATERIALS, 1991, 3 (03) :418-423

[3] LITHIUM ALUMINUM HYDRIDE, ALUMINUM HYDRIDE AND LITHIUM GALLIUM HYDRIDE, AND SOME OF THEIR APPLICATIONS IN ORGANIC AND INORGANIC CHEMISTRY [J].

FINHOLT, AE ;

BOND, AC ;

SCHLESINGER, HI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (05) :1199-1203

[4]

FUSEK J, 1976, J CHEM SOC CHEM COMM, V41, P187

[5] IONICALLY HIGH CONDUCTIVE SOLID ELECTROLYTES COMPOSED OF GRAFT COPOLYMER LITHIUM SALT HYBRIDS [J].

KOBAYASHI, N ;

UCHIYAMA, M ;

SHIGEHARA, K ;

TSUCHIDA, E .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (06) :987-991

[6]

MacCallum J. R., 1987, POLYM ELECTROLYTE RE, V1

[7]

TADA Y, 1993, MAKROMOL CHEM, V194, P2163

[8] ATTEMPTS AT LITHIUM SINGLE-IONIC CONDUCTION BY ANCHORING SULFONATE ANIONS AS TERMINATING GROUPS OF OLIGO(OXYETHYLENE) SIDE-CHAINS IN COMB-TYPE POLYPHOSPHAZENES [J].

TADA, Y ;

SATO, M ;

TAKENO, N ;

NAKACHO, Y ;

SHIGEHARA, K .

CHEMISTRY OF MATERIALS, 1994, 6 (01) :27-30

[9] LITHIUM ION CONDUCTING POLYMERIC HYBRIDS [J].

TSUCHIDA, E ;

SHIGEHARA, K .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 106 (3-4) :361-369

[10]

VINCENT CA, 1989, POLYM ELECTROLYTE RE, V2

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