Organometallic gold(I) and gold(III) complexes containing 1,3,5-triaza-7-phosphaadamantane (TPA): Examples of water-soluble organometallic gold compounds

被引：69

作者：

Mohr, F ^{[1
]}

Cerrada, E ^{[1
]}

Laguna, M ^{[1
]}

机构：

[1] Univ Zaragoza, Dept Quim Inorgan, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 03期

关键词：

D O I：

10.1021/om050852d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organometallic gold(l) complexes [Au(C equivalent to CCRR'OH)(TPA)] (R = R, = H, Me, Ph and R = Me, R' = Et) and [Au(C6F5)(TPA)] as well as the gold(Ill) complexes trans-[Au(C6F5)(2)(TPA)(2)]OTf and [Au(C6F5)(3)(TPA)] (TPA = 1,3,5-triaza-7-phosphaadamantane) were prepared and fully characterized by spectroscopic methods and, in the case of rac- [Au{C equivalent to C(Et)(Me)OH} (TPA)] and [Au(C6F5)(3)(TPA)], by X-ray crystallography. The alkynyl complexes [Au(C equivalent to CCRR'OH)(TPA)] (R = R, = H, Me and R = Me, R' = Et) represent rare examples of organometallic gold(l) complexes that are soluble and stable in water.

引用

页码：644 / 648

页数：5

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