Hierarchical Assembly of Ultranarrow Alkylamine-Coated ZnS Nanorods: A Synchrotron Surface X-Ray Diffraction Study

被引：36

作者：

Belman, Nataly ^{[1
,6
]}

Acharya, Somobrata ^{[1
,2
,6
]}

Konovalov, Oleg ^{[3
]}

Vorobiev, Alexei ^{[3
]}

Israelachvili, Jacob ^{[4
,5
]}

Efrima, Shlomo ^{[6
,7
]}

Golan, Yuval ^{[1
,6
]}

机构：

[1] Ben Gurion Univ Negev, Dept Mat Engn, IL-84105 Beer Sheva, Israel

[2] Natl Inst Mat Sci, Res Ctr Mat Nanoarchitecton MANA, WPI, Tsukuba, Ibaraki 3050044, Japan

[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France

[4] Univ Calif Santa Barbara, Dept Mat, Dept Chem Engn, Santa Barbara, CA 93106 USA

[5] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[6] Ben Gurion Univ Negev, Ilse Katz Inst Nanotechnol, IL-84105 Beer Sheva, Israel

[7] Ben Gurion Univ Negev, Dept Chem, IL-84105 Beer Sheva, Israel

来源：

NANO LETTERS | 2008年 / 8卷 / 11期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/nl802287h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The packing of anisotropic ultranarrow nanoparticles (r <= 0.5 nm) in Langmuir films was investigated for two types of nanoparticles: short ZnS wires coated with tetradecylamine and ZnS rods coated with octadecylamine. In situ grazing incidence small-angle X-ray scattering (GISAXS) revealed the formation, even under zero pressure, of ordered superstructures on the water surface consisting of alternating nanoparticles. A hierarchical "packing model" is proposed, based on GISAXS, transmission electron microscopy, thermogravimetric analysis, and grazing incidence X-ray diffraction of pure surfactant Langmuir films.

引用

页码：3858 / 3864

页数：7

共 44 条

[1] A semiconductor-nanowire assembly of ultrahigh junction density by the Langmuir-Blodgett technique
Acharya, S
Panda, AB
Belman, N
Efrima, S
Golan, Y
[J]. ADVANCED MATERIALS, 2006, 18 (02) : 210 - +
[2] Two-dimensional pressure-driven nanorod-to-nanowire reactions in Langmuir monolayers at room temperature
Acharya, S
Efrima, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) : 3486 - 3490
[3] Polarization properties and switchable assembly of ultranarrow ZnSe nanorods
Acharya, Somobrata
Panda, Asit B.
Efrima, Shlomo
Golan, Ynval
[J]. ADVANCED MATERIALS, 2007, 19 (08) : 1105 - 1108
[4] The structure of surface films Part XV - Amines
Adam, NK
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1930, 126 (802) : 526 - 540
[5] AKHMATOV AS, 1966, MOL PHYS BOUNDARY FR, P63
[6] Main and tilt transition in octadecylamine monolayers
Albrecht, O.
Matsuda, H.
Eguchi, K.
[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 284 : 166 - 174
[7] ALSNIELSEN J, 1994, PHYS REP, V246, P252
[8] ANELOVA A, 1996, LANGMUIR, V12, P5643
[9] THE STUDY OF SURFACTANT MONOLAYERS BY SURFACE PRESSURE AREA MEASUREMENT
ASTON, MS
[J]. CHEMICAL SOCIETY REVIEWS, 1993, 22 (01) : 67 - 71
[10] BELMAN N, UNPUB

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