Studies of complexation of metal cations by tris(3,6-dioxaheptyl)amine in solution

被引：23

作者：

Schroeder, G

Leska, B

Gierczyk, B

Eitner, K

Wojciechowski, G

Rózalski, B

Bartl, F

Brzezinski, B

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

[2] Humboldt Univ, Klinikum Charite, Inst Med Phys & Biophys, D-10098 Berlin, Germany

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 508卷 / 1-3期

关键词：

kinetics; FTIR; C-13; NMR; thin layer chromatography; cation complexation; tris(3,6-dioxaheptyl)amine;

D O I：

10.1016/S0022-2860(99)00011-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The complexation of some cations (Zn2+, Fe2+, Fe3+, Ni2+, Cu2+, Co2+, Pb2+, Na+, Li+, Mn2+, Cd2+, K+, Mg2+, Cr3+) by tris(3,6-dioxaheptyl)amine in various solvents was studied by the thin layer chromatography, liquid secondary ion mass spectra, FT-IR and C-13 NMR spectroscopies as well as kinetic methods. In this article, the structure of the complexes is discussed. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：129 / 138

页数：10

共 13 条

[1] FT-IR study of the nature of the proton and Li+ motions in gramicidin A and C [J].